Painting hives should meet several requirements: Protection of the wood, temperature control, ascetically not displeasing, easy to paint, and provide landmarks for bees to prevent drifting. Several of these are pretty easy and well known, outdoor latex paint, only paint the insides, light colors (particularly down here in the south). Ascetically not displeasing is really up to personal taste, I have hves painted by a four year old that are "cute" because a 4 year old did them, they style would be described in the art worl as "abstract". Easy to paint usually means bare white or other solid color.

Research shows bees can distinguish shapes and colors. So simple shapes and bee distinguishable colors.
Charges
Bend Bend Sinister
Chevron Chevron Inverted
Pall Pall Inverted
Cross Saltaire
Fess Pale
Pile Pile Inverted
Lozenge Billet
Roundel Annulet
Wavelength Human Color Human Receptors Bee ColorBee Receptors
<300 Ultraviolet (Invisible)     Ultraviolet (Invisible)  
300-380   Bee Ultraviolet?350
380-450 Violet
#8f00ff screen,#9400d3 pigment
S: 430Bee Blue
#3d00ff
 440
450-480 Blue
#0000ff
   
480-500   Bee Blue-Green
#00ffff
  
500-520 Blue-Green
#00ffff screen,#00b7eb pigment
   Bee Yellow
#a3ff00
  
520-550 Green
#00ff00
  M: 544 540
550-570 Yellow-Green
#ceff00
  L: 570  
570-600 Yellow
#ffff00
   
600-630 Orange
#ff8800
    Infrayellow (Invisible)  
630-780 Red
#ff0000
     
>780 Infrared (Invisible)    

Bees, Biology and Management by Peter G. Kevan show some patterns that bees can discriminate between and shapes recognized by bees. They include circle, square, triangle, diamond, bar at an angle, 3 vertical bars, kind of a "Y" and an X. The article on this book finishes with the following: Read this book with this caveat: If you are not already a bee geek when you start, you will be one when you finish. Don't say you weren't warned. It is a treasure of a book.

December American Bee Journal 2007

Square, Diamond, Circle, Triangle, inverted triangle

Can distinguish ring from disk: http://www.pnas.org/content/92/7/3029.full.pdf

Yellow, Blue-green, blue, ultraviolet, black, White

The major difference between the color sense of a bee and a human is that the .human eye can distinguish about sixty distinct colors in the visible spectrum, while the bee can distinguish only four different colors in the visible spectrum: yellow, blue-green, blue, and ultraviolet